The geochemistry of aliphatic and polar organic tracers in sediments from Lake Bera, Malaysia     

Noorhazlina Abu BakarKheng Soo Tay  Nasr Yousef M.J. OmarM. Radzi Bin Abas  Bernd R.T. Simoneit 《Applied Geochemistry》2011,26(8):1433-1445

The molecular distributions of homologous aliphatic lipid compounds (n-alkanes, n-alkanoic acids, n-alkanols, n-alkanals and n-alkan-2-ones) were investigated in sediments of Lake Bera, Malaysia as well as in plant waxes from the vicinity using gas chromatography-mass spectrometry. In addition, triterpenoids of the oleanane, ursane, lupane and friedelane series, and their diagenetic products were also identified. Using the aquatic proxy P_aq, it was found that the n-alkanes present in surface sediments S1, S5 and S6 correspond to an input from emergent macrophytes, whereas in sediments collected from open water (S2, S3 and S4) they correspond to input from submerged/floating macrophytes. The presence of n-alkan-2-ols, a commonly found homologous series in the sediments as well as in the plant wax, is novel here. In addition, the presence of 24-methylcycloart-22-enol and 24-ethylcycloart-22-enol in sediments as well as the plant wax of Pandanus helicopus, a dominant reed around the lake, also supports the input of plant biomarkers to the sediments. The occurrence of 5-membered ring triterpenoid derivatives as major diagenetic products of the triterpenoids identified (e.g. friedelan-2,3-dione) shows that the degradation of the organic matter in the sediments occurs mainly under oxic conditions. Also, the presence of ring-A degraded triterpenoids (dihydroputranjivic acid, 3-nor-2,4-seco-friedelane, 4α- and 4β-3-norfriedelanes, A-norfriedel-10-one, and A-norfriedel-8-en-10-one) and the aromatized triterpenoid hydrocarbons (mono- and triaromatic derivatives) as minor diagenetic products indicates photochemical and microorganism-mediated alteration reactions of natural products in the sediments. Additional novel polyfunctional friedelane derivatives, namely friedelane-2,3-dione, friedelane-1,3-diol-2-one and friedel-1(10)-ene-1,3-diol-2-one were identified for the first time in this study. These novel polyfunctional triterpenoids were inferred to derive from the oxidation of the triterpenoids from higher plants in this oxic tropical environment. For future reference purposes, the mass spectra of the identified polar triterpenoids are also presented here. This study provides important data on the biogeochemistry of organic matter in a tropical lake of SE Asia.  相似文献   

Geochemistry and fluid inclusions study of highly fractionated garnet-bearing granite of Gabal Abu Diab, central Eastern Desert of Egypt     

M. A. Mohamed  F. F. Abu El-Ela 《Arabian Journal of Geosciences》2011,4(5-6):763-773

The Neoproterozoic granite of Gabal Abu Diab, central Eastern Desert of Egypt, comprises mainly garnet-bearing granite and alkali feldspar granite intruded into calc-alkaline granodiorite–tonalite and metagabbro–diorite complexes. The garnet-bearing granite is composed mainly of plagioclase, K-feldspar, quartz, garnet and primary muscovite ± biotite. The presence of garnet and primary muscovite of Abu-Diab granite suggests its highly fractionated character. Geochemically, the garnet-bearing granite is highly fractionated as indicated from the high contents of SiO₂ (74.85–77.5%), alkalis (8.27 to 9.2%, Na₂O+K₂O) and the trace elements association: Ga, Zn, Zr, Nb and Y. This granite is depleted in CaO, MgO, P₂O₅, Sr and Ba. The alumina saturation (Shand Index, molar ratio A/CNK) of 1.0 to 1.1 indicates the weak peraluminous nature of this garnet-bearing granite. The geochemical characteristics of the Abu Diab garnet-bearing granite are consistent with either the average I-type or A-type granite and also suggest post-orogenic or anorogenic setting. A fluid inclusions study reveals the presence of three fluid generations trapped into the studied granite. The earlier is a complex CO₂–H₂O fluid trapped in primary fluid inclusions with CO₂ contents >?60 vol.%. These inclusions were probably trapped at minimum temperature >?400°C and minimum pressure >?2 kb. The second is immiscible water–CO₂ fluid trapped in secondary and/or pseudo-secondary inclusions. The trapping conditions were estimated at temperature between 400°C and 170°C and pressure between 900 and 2000 bar. The latest fluid is low-salinity aqueous fluid trapped in secondary two-phase and mono-phase inclusions. The trapping conditions were estimated at temperature between 90°C and 160°C and pressure <?900 bar. The origin of the early fluid generation is magmatic fluid while the second and third fluids are of hydrothermal and meteoric origin, respectively.  相似文献   

Amelioration of calcareous sandy soil productivity via incorporation between biochar and some organic manures     

Abu El-Eyuoon Abu Zied Amin 《Arabian Journal of Geosciences》2018,11(23):759

Most arid and semi-arid soils, especially calcareous sandy soils, are widely distributed in the Middle East region; the deficiency in their content of many nutrients particularly phosphorus and organic matter limits crops production. This study aimed to assess the effects of adding biochar (B) with farmyard manure (FYM) and poultry manure (PM) on some soil properties, phosphorus (P) availability, and barley growth in calcareous sandy soil. The pot experiment includes the following treatments: Control, B, B?+?FYM (1:1), B?+?PM (1:1), B?+?FYM (2:1), B?+?PM (2:1), FYM?+?B (2:1), and PM?+?B (2:1). Biochar combined with FYM and PM enhanced the water holding capacity (WHC) and soil organic matter (SOM) content in calcareous sandy soil. Phosphorus availability was increased significantly by applying biochar mixed with farmyard manure and poultry manure at all treatments. Green biomass of barley improved because of adding biochar alone, poultry manure alone, and biochar co-applied with poultry manure at all mixing ratios. Biochar application caused significant increases in phosphorus use efficiency (PUE) by barley plants compared to all other treatments, except for the control. We recommend adding biochar either individually or mixed with poultry manure to improve the productivity of calcareous sandy soil.  相似文献   

Environmental texture and geochemistry of the sediments of a subtropical mangrove ecosystem and surrounding areas,Red Sea Coast,Egypt     

Hashem A. Madkour  Abbas M. Mansour  Abu El-Hagag N. Ahmed  A. El-Taher 《Arabian Journal of Geosciences》2014,7(9):3427-3440

The textural and geochemical aspects of the sediments of subtropical mangrove ecosystem and surrounding areas have been studied and discussed. Forty sediment samples were collected from different areas of mangrove environment and surrounding areas along the Egyptian Red Sea coast. The sediments of each study areas are characterized by the abundance of sand with minor amounts of mud and gravel. The mean size of the sediments ranged from medium grained to fine grained at the study areas. Cluster analysis showed that the distribution of gravel, sand, and mud fractions is related to bottom facies and type of sediment source. Generally, sand fraction is the main category among the three constituents. Carbonate content recorded minor values in the study areas. The CaCo₃ content of the sediments ranged from 4.7 % at Hamata area to 64.9 % at Erier area. Terrigenous and biogenic components are the factor controlling of the carbonate content of studies sediments. The organic carbon content ranged from 1.10 at Hamata area to 3.1 % at Sharm el-Qibli and Erier areas, which is controlled by particle size of the sediments. Phosphorus content in the different studied localities is related to the sources of phosphorus to the area. Our observations provide evidence that there are no significant differences in environmental texture and geochemistry of the sediments of subtropical mangrove ecosystem and surrounding areas of the Egyptian Red Sea coast.  相似文献   

Geomechanical evaluation of Pliocene natural aggregates as pavement materials     

El-Sayed Sedek Abu Seif 《Arabian Journal of Geosciences》2014,7(4):1567-1576

Asphaltic roads and constructions in Egypt annually consume a huge amount of aggregates. The physical and geomechanical properties of these aggregates have controlled their performance in which they are used. All road pavements require the efficient use of locally available materials if economically constructed roads are to be built. More than 650 million m³ of fine and coarse aggregates are herein selected to be the tonnage of the present study. The studied Pliocene aggregates have smoothed grading curves and neither a deficiency nor excess of any one particle size, generally produce good mixtures with fewer voids between particles. The litho-particles of coarse aggregates are composed mainly of granites, gneisses, granodiorite, gabbro, and quartz particles. The sand equivalent value of fine aggregates varies from 95 to 97 %. The specific gravity values of the studied aggregates vary from 2.72 to 2.74 gm/cm³ for coarse aggregate and range from 2.51 to 2.54 gm/cm³ for fine aggregate. The Los Angles abrasion value varies from 19 to 24 %. Both coarse and fine aggregates meet the international standards which are suitable for usage as subbase and surface course aggregates, respectively.  相似文献   

Evaluation of Fragments from Disc Cutting of Dry and Saturated Sandstone     

M. Z. Abu Bakar  L. S. Gertsch  J. Rostami 《Rock Mechanics and Rock Engineering》2014,47(5):1891-1903

As the use of mechanical excavation in tunneling and mining activities expands, so has the use of disc cutters in various ground conditions. The impact of moisture content on rock behavior and rock excavation by disc cutters is examined in this study. This was done through a series of full-scale cutting tests using a 292 mm (11.5 in.) disc cutter in a moderate strength sandstone. The muck from the cutting tests was used to determine coarseness index (CI) and absolute size constant (x′). x′ was calculated using Rosin–Rammler distribution (or Weibull) curve, a statistical technique to look at the fragmented rock products. This approach is very popular among the mineral-processing professionals for the evaluation of the particle sizes of the comminution products. x′ and CI show a reasonable correlation with the specific energy of cutting and production rate. Both of these indicators were found to be dependent on the cut spacing and the interaction between the adjacent cuts, as anticipated. This paper explains the background information on this topic, reviews the laboratory testing, and offers analysis of the results of grain size distribution and its relationship with specific energy and cutting geometry. It should be noted that the experimental program was limited to only one rock type and additional testing on the other rock types is required to expand the results of the current study.  相似文献   

Head—on collision of nonlinear dust—acoustic solitary waves in dusty plasmas with dust of opposite polarities     

S. K. El-Labany  E. F. El-Shamy  M. Abu El-Eneen 《Astrophysics and Space Science》2012,337(1):275-281

The propagation and the head—on collision of nonlinear dust—acoustic solitary waves (DASWs) in dusty plasmas consisting of electrons, ions and negative as well as positive dust particles are investigated. Applying an extended Poincaré-Lighthill-Kuo (PLK) method, Kortwege-de Vries equations and analytical phase shifts after the head-on collision of two DASWs in dusty plasmas are obtained. Analytically and numerically, the relevance of the phase shifts and trajectories to the positive-to-negative dust number density ratio, the ratio of the ion number density to negative dust number density, negative-to-positive dust particle mass ratio, and the ion-to-electron temperature ratio effects is explicitly demonstrated. Moreover, the current findings are applied to different regions of space, viz. cometary tails, mesosphere, Jupiter’s magnetosphere.  相似文献   

Coupling of remote sensing data and environmental-related parameters for dengue transmission risk assessment in Subang Jaya,Malaysia     

Nazri Che Dom  Abu Hassan Ahmad  Zulkiflee Abd Latif  Rodziah Ismail 《国际地球制图》2013,28(3):258-272

In Malaysia, the endemic level of dengue fever (DF) has already changed morbidity indicators, and the magnitude of these incidences in the last few years has surpassed the incidences of all other diseases of compulsory notification. The reasons for the dramatic emergence of DF are complex and not well understood. There are many factors that contribute to the epidemiological conditions that favour viral transmission by the main mosquito vector. This study, therefore, is filling this gap by analysing the impact of dengue incidence at a local (Subang Jaya) scale using environmental factors. Meteorological data and land-use pattern were consolidated using geographic information system (GIS) and its components as an analytical tool. We have shown that weather variables (relative humidity, temperature and precipitation) have significant correlation with DF incidence with seasonal variation. Besides land-use pattern, DF incidence shows the higher distribution in the residential area, followed by commercial and industrial area. This is due to the higher population density in residential area as well as favourable places for the breeding of dengue-carrying Aedes mosquitos created by humans in the residential area, especially one-storey houses. The analysis on the trends of DF incidence towards various housing types indicate that most of the victims’ houses fall into interconnection houses and mixed houses types compared to the independent houses area. The outcome driven from this analysis suggested that each character of the environmental factors has their own risk towards dengue incidence. In line with that, it is possible to develop a dynamic model of DF transmission using the knowledge produced by this comprehensive time series data and the results provided by the different analyses.  相似文献   

Effect of Ozone and Ozone/Fenton in the Advanced Oxidation Process on Biodegradable Characteristics of Semi‐aerobic Stabilized Leachate     

Salem S. Abu Amr  Hamidi Abdul Aziz  Mohd Nordin Adlan  Shuokr Qarani Aziz 《洁净——土壤、空气、水》2013,41(2):148-152

This study investigated the effects of O₃ and O₃/H₂O₂/Fe²⁺ in the advanced oxidation processes (AOPs) on the biodegradable and soluble characteristics of semi‐aerobic stabilized solid waste leachate. The biodegradability (BOD₅/chemical oxygen demand, COD) ratio improved from 0.034 to 0.05 and 0.1 following O₃ and O₃/H₂O₂/Fe²⁺, respectively. Fractions of biodegradable COD_(bi) (24%), non‐biodegradable COD_(ubi) (76%), soluble COD_(s) (59%), biodegradable soluble COD_(bsi) (38%), non‐biodegradable soluble COD_(ubsi) (62%), and particulate COD (PCOD) (41%) in stabilized leachate were also investigated. The fraction of COD_(bi) increased to 28 and 36% after applying O₃ and O₃/AOPs, respectively. COD_(S) increased to 59% after O₃ and to 72% after O₃/AOPs, whereas COD_(bsi) increased to 38 and 51% after O₃ and O₃/AOPs, respectively. The removal efficiency of COD_(S) was obtained at 5% after O₃ alone and improved to 51% following ozone‐based AOPs, whereas the removal efficiency of PCOD improved from 25% after O₃ to 71% after ozone‐based AOPs.  相似文献   

Removal of Bromate from Water Using De‐Acidite FF‐IP Resin and Determination by Ultra‐Performance Liquid Chromatography‐Tandem Mass Spectrometry     

Mu. Naushad  Zeid A. ALOthman  Mohammad R. Khan  Saikh M. Wabaidur 《洁净——土壤、空气、水》2013,41(6):528-533

Contamination of water due to bromate is a severe health hazard. The aim of the present study was to remove bromate from water using a crosslinked polystyrene based strongly basic anion exchange resin De‐Acidite FF‐IP. Batch experiments were performed to study the influence of various experimental parameters such as effect of pH, contact time, temperature, and effect of competing anions on bromate removal by De‐Acidite FF‐IP resin. At optimum parameters, the removal rate of bromate was very fast and 90% removal took place in 5 min and equilibrium was established within 10 min. The presence of competitive anions reduced the bromate adsorption in the order of Cl^? > F^? > CO > SO > NO > PO. The practical utility of this resin has been demonstrated by removing bromate in some of the commercial bottled water from Saudi Arabia. The level of bromate was determined using a very sensitive, precise and rapid method based on ultra‐performance liquid chromatography‐tendem mass spectrometry (UPLC‐MS/MS).  相似文献